PHYSICAL PROPERTIES
Selected physical properties for canola oil are shown in Table 1.
Table 1. Physical Properties of Canola Oil
Parameter
Value
Relative Density (g/cm3; 20°C/water at 20°C)
0.914 - 0.917
Refractive Index (nD 40°C)
1.465 - 1.467
Crismer Value
67 - 70
Viscosity (Kinematic at 20°C, mm2/sec)
78.2
Cold Test (15 Hrs at 4°C)
Passed
Smoke Point (°C)
220 - 230
Flash Point, Open cup (°C)
275 - 290
Specific Heat (J/g at 20°C)
1.910 - 1.916
Thermal Conductivity (W/m°K)
0.179 - 0.188
Relative Density
The relative density of canola oil was first reported by Ackman and Eaton
in 1977 and later confirmed by Vadke et al. (1988) and Lang et al. (1992).
Noureddini et al. (1992) reported a density for high erucic acid rapeseed
oil of 0.9073 g/cm3 while Appelqvist & Ohlson (1972) reported a range
from 0.906 g/cm3 to 0.914 g/cm3. Ackman and Eaton (1977) indicated
that a different proportion of eicosenoic (C20:1) and C18 polyunsaturated
acids could be a major factor for the increase in relative density of canola
oil. The higher specific gravity of 0.9193 g/cm3 observed for soybean oil
can be attributed to the higher content of linoleic acid (Ackman and
Eaton, 1977). As for other liquids, the density of vegetable oils is temper-
ature dependent and decreases in value when temperature increases
(Figure 1).
Crismer Value
The Crismer Value measures the miscibility of an oil in a standard solvent
mixture, composed of t-amyl alcohol, ethyl alcohol and water in the vol-
ume proportion 5:5:0.27. Crismer value (CV) is one of the specification
criteria used for international trade, mostly in Europe. Characteristic val-
ues are usually within a narrow limit (AOCS, 1992). The miscibility of an
oil is related to the solubility of glycerides, and is affected mainly by the
unsaturation and chain length of the constituent fatty acids. Little data is
available describing the solubility characteristics of canola oil.
Sahasrabudhe (1977) found that the Crismer value decreased from 82.0
to 76.8 with the reduction of erucic acid content from 54 to 0.1%.
Viscosity
Viscosity values estimate an oils relative thickness or resistance to flow.
Viscosity of refined, bleached and deodorized (RBD) canola is higher
than soybean oil (Figure 2).
of canola and other vegetable oils, like other liquids, was affected by
temperature and proposed an equation to calculate viscosity in the
temperature range from 4 to 100°C. Figure 2 shows the relation
between temperature and viscosity for canola and selected vegetable oils.
Rapeseed oil exhibited a higher viscosity than canola, corn and soybean
oils. This can be directly related to the contribution of saturated fatty
acids (Noureddini et al., 1992a).
Canola Oil:
Physical and Chemical Properties
by Dr. Roman Przybylski
Canola oil produced in Canada is obtained from the seeds of Brassica napus and Brassica rapa. These cultivars, low in erucic acid
and glucosinolates, are very different from high erucic acid rapeseed oil in chemical, physical and nutritional properties.
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